Phase II Site Assessments - Learn More
LIGHT HYDROCARBON ANALYSES
Light hydrocarbon analyses (C1-C4) measure the lightest, most volatile compounds present in natural gas and other petroleum based products. These light hydrocarbon compounds tend to dissipate rapidly with time and/or distance from the point(s) at which petroleum products are introduced into the subsurface environment. The light hydrocarbon analyses allow for the identification and differentiation of natural gas leaks, biogenic methane and refined petroleum product contaminants. Light hydrocarbon compound analyses are also utilized to determine areas of natural gas leakage spills, the presence of gas seepage from deep seated oil and gas reservoirs and/or the leakage from oil and gas well casings.
HIGH RESOLUTION GC C5+ (PENTANE-XYLENES) HYDROCARBON ANALYSES/SOIL VAPOR AND/OR WATER
C5+ (pentane-xylenes+) hydrocarbons analyses yield a quantitative measure of the actual volume of "gasoline type " vapors present in near surface soils and/or water. Gasoline range hydrocarbons dissipate more slowly than the lighter fraction (C1-C4) compounds. If specific BTEX analyses are required, a FID equipped with a capillary column is used to quantify benzene, toluene, ethylbenzene, m &p-xylene and o-xylene aromatic hydrocarbons.
ANALYSIS FOR FIXED GAS (CO2, O2, N2)
If petroleum and/or chlorinated hydrocarbon products are present in subsurface soils or groundwater for a period of time, significant biodegradation of the hydrocarbon compounds occurs. The degradation of hydrocarbon compounds by aerobic and anaerobic bacteria generate significant concentrations of carbon dioxide and methane, respectively, in the subsurface environment. The biodegradation of hydrocarbons by both aerobic and anaerobic bacteria can occur within very close proximity in nature, and can yield elevated concentrations of both carbon dioxide and methane in the subsurface environment. These biochemical reactions are quite common in soils and groundwater containing products such as gasoline, diesel, chlorinated solvents, etc. since such products are excellent food sources for the indigenous bacteria. Carbon dioxide analyses, as well as oxygen and nitrogen, are also performed using a gas chromatograph equipped with a thermal conductivity detector (TCD). The results of these analyses used in tandem with the petroleum and chlorinated hydrocarbon analyses aid in the delineation of the subsurface contaminant plume(s).
CHLORINATED HYDROCARBONS
Soil gas assessments for chlorinated hydrocarbons include analyses for PCE, DCE, TCE, vinyl chloride and other chlorinated solvents using a dual detector gas chromatograph equipped with an electron capture detector (ECD) and flame ionization detector (FID). The instrument is excellent for quantifying various chlorinated solvents, and their daughter products, commonly found in subsurface soils and groundwater. Light (C1-C4) hydrocarbon analyses also provide valuable information when used in tandem with chlorinated hydrocarbon constituent analyses. Elevated concentrations of ethylene (ethene) and ethane (and methane), in areas where elevated concentrations of chlorinated hydrocarbon compounds are present, are indicative of anaerobic biodegradation of chlorinated solvents. Most chlorinated solvents contain either ethane or ethene in their molecular structures, and these more volatile compounds are very helpful in delineating the full areal extent of the subsurface contamination.
MAPPING AND INTERPRETATION
Contaminant plume maps are routinely constructed for a variety of hydrocarbon constituents. These plume maps are used by ETI personnel to identify the source(s) and possible migration pathways of contaminants. Hydrocarbon compound ratios and chromatograms are utilized to define distinct plumes resulting from different sources, to delineate plumes resulting from the commingling of two or more products and/or the matching of liquid products with soil gas sample data. The component ratios and chromatographic signatures can also be used to delineate areas where the contamination is a result of either recent or old product releases and to provide some evidence of aging where the contamination is due to the weathering of a product lost in the past. The soil gas studies conducted by ETI are invaluable in determining the horizontal extent of contaminant plumes in the subsurface environment. Soil gas plume maps can be utilized to determine the locations at which boreholes and/or monitoring wells should be placed. The use of these soil gas maps can eliminate "random "drilling and supplement the data acquired from soil sample analyses. The information obtained during the performance of a soil vapor survey is extremely cost-effective since the density of the data collected greatly exceeds that achieved through borehole and/or monitor well drilling. In addition, fewer boreholes/monitor wells are required to delineate the vertical extent of contamination after using the soil gas plume maps as a "drilling guide".
HIGH RESOLUTION GC OF PRODUCT AND SOIL EXTRACTS
High resolution detailed fingerprints are utilized to correlate product accumulations with source of contamination and areal distribution of vapor and dissolved phase constituents in soil and water. High resolution GC of hydrocarbon extracts from soil provides delineation of the areal and vertical extent and type product contamination. These analyses are available with individual component quantification.